On 24 March 1990, he was elected the first President of the Republic by the Uzbek Supreme Soviet. From 1990 to 1991, he served as a member of the Central Committee and Politburo. In 1989, he became first secretary of the Central Committee of the Communist Party of the Uzbek SSR, after his predecessor Rafiq Nishonov failed to quell inter-ethnic clashes and instability in the Fergana Region. In 1986, Karimov assumed the post of first secretary of the Kashkadarya Regional Committee of the Communist Party of Uzbekistan Committee of the Communist Party of the Uzbek SSR. įrom 1966 to 1986, he worked his way up the ranks in the Uzbek State Planning Committee, from chief specialist, to department head, to Minister of Finance of the Uzbek SSR, chairman of the State Planning Committee and deputy chairman of the Council of Ministers of the Uzbek SSR. In 1967, he earned a master's degree in economics from Tashkent State University of Economics. He began work as an engineer, eventually joining the Ministry of Water Resources of the Uzbek Soviet Socialist Republic. In 1960, he graduated from the Central Asian Polytechnic Institute (now Tashkent State Technical University) with a degree in mechanical engineering. He was sent to an orphanage in 1941, brought back in 1942, and then returned to the orphanage in 1945. But according to unofficial data his biological father was Bukharan Jewish. According to official data his father is Abdug'ani Karimov, an Uzbek, and his mother is Sanobar Karimova, a Tajik. Karimov was born in Samarkand to Uzbek parents who were civil servants. He ruled a repressive authoritarian regime in Uzbekistan where political opponents were assassinated, human rights were repressed, and dissent was prohibited. He died from a stroke on 2 September 2016, after being president of the country for 25 years. Karimov's first presidential term was extended to 2000 by way of a referendum, and he was re-elected in 2000, 20, each time receiving over 90% of the vote. Foreign observers and opposition party cited voting irregularities, alleging state-run propaganda and a falsified vote count. He subsequently won a non-democratic presidential election on 29 December 1991, with 86% of the vote. He declared Uzbekistan an independent nation on 31 August 1991. He was the President of the Uzbek SSR from 24 March 1990 until he declared the independence of Uzbekistan on 1 September 1991. He was the last First Secretary of the Communist Party of Uzbekistan from 1989 to 1991, when the party was reconstituted as the People's Democratic Party of Uzbekistan (PDP) he led the PDP until 1996. Chem Rec 7: 12–23 2007: Published online in Wiley InterScience ( DOI 10.1002/tcr.Islam Abduganiyevich Karimov ( Uzbek: Islom Abdugʻaniyevich Karimov / Ислом Абдуғаниевич Каримов Russian: Ислам Абдуганиевич Каримов 30 January 1938 – 2 September 2016) was the leader of Uzbekistan and its predecessor state, the Uzbek Soviet Socialist Republic, from 1989 until his death in 2016. © 2007 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. It is noted that the use of water and BF 3-Et 2O is crucial to the success of this α-acetoxylation. The oxidation of a ketone with m-CPBA in acetic acid in the presence of a catalytic amount of iodobenzene, BF 3-Et 2O, and water at room temperature affords an α-acetoxy ketone in good yield. The latter part reports on the iodobenzene-catalyzed α-oxidation of ketones, in which diacyloxy(phenyl)-λ 3-iodanes generated in situ act as real oxidants of ketones and m-chloroperbenzoic acid ( m-CPBA) serves as a terminal oxidant. Thus, the complexes undergo oxidative transformations of a variety of functional groups such as olefins, alkynes, enones, silyl enol ethers, sulfides, and phenols under mild conditions. These crown ether complexes are highly reactive and serve as versatile stoichiometric oxidants, especially in water.
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